Permeability-Modifying Drilling Fluids and Methods of Use

ABSTRACT

Drilling fluids comprising a base fluid and a hydrophobically modified polymer. The hydrophobically modified polymer consisting of alkyl chains having a carbon chain length between about 4 and about 22 carbons bound to a hydrophilic polymer. The hydrophilic polymer (1) consists of a polymer backbone that contains polar heteroatoms, at least one of which is not a nitrogen atom, and at least a portion of the polar heteroatoms are functionalized with the alkyl chains; and, (2) comprises at least one hydrophilic polymer selected from the group consisting of a cellulose, a chitosan, a polyetheramine, a polyhydroxyetheramine, a polylysine, and a polysulfone.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation-in-part of U.S. application Ser. No.10/760,443 entitled Methods and Compositions for Reducing the Productionof Water and Stimulating Hydrocarbon Production from a SubterraneanFormation, filed on Jan. 20, 2004.

BACKGROUND OF THE INVENTION

The present invention relates to subterranean drilling operations, andmore particularly, the present invention relates to methods andcompositions for reducing the permeability of a subterranean formationto aqueous-based fluids during the drilling phase.

The process of drilling a well bore in a subterranean formationtypically requires the use of a drilling fluid. During the drillingprocess, the drilling fluid is passed down through the inside of thedrill string, exits through the drill bit, and returns to the surfacethrough the annulus between the drill string and the well bore. Amongother things, the circulating drilling fluid lubricates the drill bit,carries drill cuttings to the surface, and balances the formationpressure exerted on the well bore. This process in the life of a well isknown as the “drilling phase.” It is understood that there is also a“production phase” in the life of a well, during which hydrocarbons orother desired substances may be produced.

While well bores usually are drilled in hydrocarbon-producingformations, the formations may contain layers of water or may be locatedadjacent to water-producing zones. The high mobility of water may allowit to flow into the well bore by way of natural fractures and/or highpermeability streaks present in the formation. Over the life of suchwells, the ratio of water to hydrocarbons recovered often becomes sohigh that the cost of producing the water, separating it from thehydrocarbons, and disposing of this water may represent a significanteconomic loss. Besides being highly undesirable during the productionphase, water-producing zones may cause problems in the well bore withcertain completions activities. However, these problems with theproduction of undesired water generally are not addressed during thedrilling phase.

To reduce the production of undesired water from hydrocarbon-producingformations, aqueous polymer solutions that may contain cross-linkingagents have been used. Such polymer solutions are injected into theformation and cross-linked to form stiff gels that may stop or reducethe flow of the undesired water. Even when a polymer solution isproperly placed in a water-producing section, however, the cross-linkedgels formed may not remain stable in the zone due to thermal degradationand/or differences in the adsorption characteristics of the polymer,associated cross-linker, and the like. Further, the selected placementof a polymer solution in a producing formation may require expensive,time-consuming mechanical zonal isolation. Zonal isolation also may beinaccurate, which may lead to plugging and/or damaging thehydrocarbon-bearing sections. Damage to hydrocarbonproducing pathways isundesirable.

Recently, wells in the production phase have been treated with compoundsto reduce the production of water with hydrocarbons. These compounds arecommonly referred to as “relative permeability modifiers.” Relativepermeability modifiers, such as polyacrylamide, may be dissolved inwater and pumped into a subterranean formation that produces water andhydrocarbons, reducing the permeability of the formation to waterwithout substantially affecting the permeability therein tohydrocarbons. The use of these relative permeability modifiers, however,has resulted in only small temporary reductions in water productionand/or unacceptable levels of reduction in hydrocarbon production.Further, conventional relative permeability modifiers heretofore havenot been used in the drilling phase.

SUMMARY OF THE INVENTION

The present invention relates to subterranean drilling operations, andmore particularly, the present invention relates to methods andcompositions for reducing the permeability of a subterranean formationto aqueous-based fluids during the drilling phase.

Some embodiments of the present invention provide a method of reducingthe permeability of a subterranean formation to aqueous-based fluidsduring the drilling phase that comprises the steps of providing awater-soluble relative permeability modifier that comprises ahydrophobically modified polymer; and placing the water-soluble relativepermeability modifier into the subterranean formation during thedrilling phase.

Another embodiment of the present invention provides a method ofreducing the permeability of a subterranean formation to aqueous-basedfluids during the drilling phase that comprise the steps of providing awater-soluble relative permeability modifier that comprises ahydrophilically modified polymer; and placing the water-soluble relativepermeability modifier into the subterranean formation during thedrilling phase.

Another embodiment of the present invention provides a method ofreducing the permeability of a subterranean formation to aqueous-basedfluids during the drilling phase that comprises the steps of providing awater-soluble relative permeability modifier that comprises awater-soluble polymer without hydrophobic or hydrophilic modification;and placing the water-soluble relative permeability modifier into thesubterranean formation during the drilling phase.

Some embodiments of the present invention provide a method of drilling awell bore in a subterranean formation that comprises the steps ofproviding a drilling fluid that comprises a base fluid, and awater-soluble relative permeability modifier that comprises ahydrophobically modified polymer; and placing the drilling fluid in thewell bore in the subterranean formation.

Another embodiment of the present invention provides a method ofdrilling a well bore in a subterranean formation that comprises thesteps of providing a drilling fluid that comprises a base fluid, and awater-soluble relative permeability modifier that comprises ahydrophilically modified polymer; and placing the drilling fluid in thewell bore in the subterranean formation.

Another embodiment of the present invention provides a method ofdrilling a well bore in a subterranean formation that comprises thesteps of providing a drilling fluid that comprises a base fluid, and awater-soluble polymer without hydrophobic or hydrophilic modification;and placing the drilling fluid in the well bore in the subterraneanformation.

Another embodiment of the present invention provides a drilling fluidthat comprises a base fluid, and a water-soluble relative permeabilitymodifier that comprises a hydrophobically modified polymer.

Yet another embodiment of the present invention provides a drillingfluid that comprises a base fluid, and a water-soluble relativepermeability modifier that comprises a hydrophilically modified polymer.

The features and advantages of the present invention will be readilyapparent to those skilled in the art upon a reading of the descriptionof the exemplary embodiments which follows.

DESCRIPTION OF EXEMPLARY EMBODIMENTS

The present invention relates to subterranean drilling operations, andmore particularly, the present invention relates to methods andcompositions for reducing the permeability of a subterranean formationto aqueous-based fluids during the drilling phase.

In certain embodiments of the present invention, the water-solublerelative permeability modifiers comprise hydrophobically modifiedpolymers. As used herein, “water-soluble” refers to at least 0.01 weightpercent soluble in distilled water. As used herein, “hydrophobicallymodified” refers to the incorporation into the hydrophilic polymerstructure of hydrophobic groups, wherein the alkyl chain length is fromabout 4 to about 22 carbons. In another embodiment of the presentinvention, the water-soluble relative permeability modifiers comprisehydrophilically modified polymers. As used herein, “hydrophilicallymodified” refers to the incorporation into the hydrophilic polymerstructure of hydrophilic groups. In yet another embodiment of thepresent invention, the water-soluble relative permeability modifierscomprise water-soluble polymers without hydrophobic or hydrophilicmodification.

The hydrophobically modified polymers that may be used in the presentinvention typically have a molecular weight in the range of from about100,000 to about 10,000,000. In an exemplary embodiment, thehydrophobically modified polymers may comprise a polymer backbone thatcomprises polar heteroatoms. Generally, the polar heteroatoms presentwithin the polymer backbone of the hydrophobically modified polymersinclude, but are not limited to, oxygen, nitrogen, sulfur, orphosphorous.

In certain embodiments of the present invention, the hydrophobicallymodified polymers may be a reaction product of a hydrophilic polymer anda hydrophobic compound. The hydrophilic polymers suitable for formingthe hydrophobically modified polymers used in the present inventionshould be capable of reacting with hydrophobic compounds. Suitablehydrophilic polymers include, homo-, co-, or terpolymers such as, butnot limited to, polyvinylamines, poly(vinylamines/vinyl alcohols), andalkyl acrylate polymers in general. Additional examples of alkylacrylate polymers include, but are not limited to,polydimethylaminoethyl methacrylate, polydimethylaminopropylmethacrylamide, poly(acrylamide/dimethylaminoethyl methacrylate),poly(methacrylic acid/dimethylaminoethyl methacrylate),poly(2-acrylamido-2-methyl propane sulfonic acid/dimethylaminoethylmethacrylate), poly(acrylamide/dimethylaminopropyl methacrylamide), poly(acrylic acid/dimethylaminopropyl methacrylamide), and poly(methacrylicacid/dimethylaminopropyl methacrylamide). In certain embodiments, thehydrophilic polymers contain reactive amino groups in the polymerbackbone or as pendant groups, which are capable of reacting withhydrophobic compounds. In an exemplary embodiment, the hydrophilicpolymers comprise dialkyl amino pendant groups. In an exemplaryembodiment, the hydrophilic polymers comprise a dimethyl amino pendantgroup and at least one monomer comprising dimethylaminoethylmethacrylate or dimethylaminopropyl methacrylamide. In certain exemplaryembodiments of the present invention, the hydrophilic polymers comprisea polymer backbone that comprises polar heteroatoms, wherein the polarheteroatoms present within the polymer backbone of the hydrophilicpolymers include, but are not limited to, oxygen, nitrogen, sulfur, orphosphorous. Suitable hydrophilic polymers comprising polar heteroatomswithin the polymer backbone include homo-, co-, or terpolymers, such as,but not limited to, celluloses, chitosans, polyamides, polyetheramines,polyethyleneimines, polyhydroxyetheramines, polylysines, polysulfones,and starches. In an exemplary embodiment, the starch is a cationicstarch. A suitable cationic starch may be formed by reacting a starch,such as corn, maize, waxy maize, potato, tapioca, and the like, with thereaction product of epichlorohydrin and trialkylamine.

The hydrophobic compounds that are capable of reacting with thehydrophilic polymers of the present invention include, but are notlimited to, alkyl halides, sulfonates, sulfates, and organic acidderivatives. Examples of suitable organic acid derivatives include, butare not limited to, octenyl succinic acid; dodecenyl succinic acid; andanhydrides, esters, and amides of octenyl succinic acid or dodecenylsuccinic acid. In certain exemplary embodiments, the hydrophobiccompounds may have an alkyl chain length of from about 4 to about 22carbons. For example, where the hydrophobic compound is an alkyl halide,the reaction between the hydrophobic compound and hydrophilic polymermay result in the quaternization of at least some of the hydrophilicpolymer amino groups with an alkyl halide, wherein the alkyl chainlength is from about 4 to about 22 carbons.

In another embodiment of the present invention, the water-solublerelative permeability modifiers of the present invention comprise ahydrophilically modified polymer. The hydrophilically modified polymersused in the present invention typically have a molecular weight in therange of from about 100,000 to about 10,000,000. In an exemplaryembodiment, the hydrophilically modified polymers comprise a polymerbackbone that comprises polar heteroatoms. Generally, the polarheteroatoms present within the polymer backbone of the hydrophilicallymodified polymers include, but are not limited to, oxygen, nitrogen,sulfur, or phosphorous.

In certain embodiments of the present invention, the hydrophilicallymodified polymer may be a reaction product of a hydrophilic polymer anda hydrophilic compound. The hydrophilic polymers suitable for formingthe hydrophilically modified polymers used in the present inventionshould be capable of reacting with hydrophilic compounds. In certainexemplary embodiments, suitable hydrophilic polymers include, homo-,co-, or terpolymers, such as, but not limited to, polyvinylamines,poly(vinylamines/vinyl alcohols), and alkyl acrylate polymers ingeneral. Additional examples of alkyl acrylate polymers include, but arenot limited to, polydimethylaminoethyl methacrylate,polydimethylaminopropyl methacrylamide,poly(acrylamide/dimethylaminoethyl methacrylate), poly(methacrylicacid/dimethylaminoethyl methacrylate), poly(2-acrylamido-2-methylpropane sulfonic acid/dimethylaminoethyl methacrylate),poly(acrylamide/dimethylaminopropyl methacrylamide), poly (acrylicacid/dimethylaminopropyl methacrylamide), and poly(methacrylicacid/dimethylaminopropyl methacrylamide). In certain embodiments, thehydrophilic polymers contain reactive amino groups in the polymerbackbone or as pendant groups, which are capable of reacting withhydrophilic compounds. In an exemplary embodiment, the hydrophilicpolymers comprise dialkyl amino pendant groups. In an exemplaryembodiment, the hydrophilic polymers comprise a dimethyl amino pendantgroup and at least one monomer comprising dimethylaminoethylmethacrylate or dimethylaminopropyl methacrylamide. In another exemplaryembodiment, the hydrophilic polymers comprise a polymer backbonecomprising polar heteroatoms, wherein the polar heteroatoms presentwithin the polymer backbone of the hydrophilic polymers include, but arenot limited to, oxygen, nitrogen, sulfur, or phosphorous. Suitablehydrophilic polymers comprising polar heteroatoms within the polymerbackbone include homo-, co-, or terpolymers, such as, but not limitedto, celluloses, chitosans, polyamides, polyetheramines,polyethyleneimines, polyhydroxyetheramines, polylysines, polysulfones,and starches. In an exemplary embodiment, the starch is a cationicstarch. A suitable cationic starch may be formed by reacting a starch,such as corn, maize, waxy maize, potato, tapioca, and the like, with thereaction product of epichlorohydrin and trialkylamine.

The hydrophilic compounds suitable for reaction with the hydrophilicpolymers include polyethers comprising halogen; sulfonates; sulfates;and organic acid derivatives. Examples of suitable polyethers include,but are not limited to, polyethylene oxides, polypropylene oxides,polybutylene oxides, and mixtures thereof. In an exemplary embodiment,the polyether comprises an epichlorohydrin terminated polyethylene oxidemethyl ether.

The hydrophilically modified polymers formed from the reaction of ahydrophilic polymer with a hydrophilic compound may have estimatedmolecular weights in the range of from about 100,000 to about 10,000,000and may have weight ratios of the hydrophilic polymers to the polyethersin the range of from about 1:1 to about 10:1. Suitable hydrophilicallymodified polymers having molecular weights and weight ratios in theranges set forth above include, but are not limited to, the reactionproduct of polydimethylaminoethyl methacrylate with epichlorohydrinterminated polyethyleneoxide methyl ether; the reaction product ofpolydimethylaminopropyl methacrylamide with epichlorohydrin terminatedpolyethyleneoxide methyl ether; and the reaction product ofpoly(acrylamide/dimethylaminopropyl methacrylamide) with epichlorohydrinterminated polyethyleneoxide methyl ether. In an exemplary embodiment,the hydrophilically modified polymer comprises the reaction product of apolydimethylaminoethyl methacrylate with epichlorohydrin terminatedpolyethyleneoxide methyl ether having a weight ratio ofpolydimethylaminoethyl methacrylate to epichlorohydrin terminatedpolyethyleneoxide methyl ether of 3:1.

In another embodiment of the present invention, the water-solublerelative permeability modifiers comprise a water-soluble polymer withouthydrophobic or hydrophilic modification. Examples of suitablewater-soluble polymers include, but are not limited to, homo-, co-, andterpolymers of acrylamide, 2-acrylamido-2-methyl propane sulfonic acid,N,N-dimethylacrylamide, vinyl pyrrolidone, dimethylaminoethylmethacrylate, acrylic acid, dimethylaminopropylmethacrylamide, vinylamine, vinyl acetate, trimethylammoniumethyl methacrylate chloride,methacrylamide, hydroxyethyl acrylate, vinyl sulfonic acid, vinylphosphonic acid, methacrylic acid, vinyl caprolactam, N-vinylformamide,N,N-diallylacetamide, dimethyldiallyl ammonium halide, itaconic acid,styrene sulfonic acid, methacrylamidoethyltrimethyl ammonium halide,quaternary salt derivatives of acrylamide and quaternary saltderivatives of acrylic acid.

In certain embodiments of the present invention, the water-solublerelative permeability modifiers of the present invention may be placedinto a subterranean formation during the drilling phase. As filtratefrom the drilling fluids leaks off into the subterranean formation, itis believed that the water-soluble relative permeability modifier, amongother things, may attach to surfaces within the subterranean formation.The presence of the water-soluble relative permeability modifiers in thesubterranean formation may reduce the permeability of the treated zonesof the subterranean formation to aqueous-based fluids (e.g., water)without substantially changing the permeability to hydrocarbons. Thismay reduce the subsequent problems associated with water flowing intothe well bore from the subterranean formation.

In one embodiment of the present invention, the water-soluble relativepermeability modifiers of the present invention may be placed into thesubterranean formation in a drilling fluid that comprises thewater-soluble relative permeability modifiers. The drilling fluids ofthe present invention generally comprise a base fluid and awater-soluble relative permeability modifier of the present invention.Moreover, other additives suitable for use in drilling fluids optionallymay be added to the drilling fluids of the present invention as desired.

The base fluid utilized in the drilling fluids of the present inventionmay comprise aqueous-based fluids, oil-based fluids, or mixturesthereof. Where the base fluid is aqueous-based, the water utilized canbe fresh water, salt water (e.g., water containing one or more saltsdissolved therein), brine (e.g., saturated salt water), or seawater.Generally, the water may be from any source provided that it does notcontain an excess of compounds that may adversely affect othercomponents in the drilling fluid. Where the base fluid is oil-based,examples of suitable oils include, but are not limited to, mineral oils,synthetic oils, esters and the like. Generally, any oil that can beemulsified is suitable for use as a base fluid in the drilling fluids ofthe present invention. It should be understood that where oil-baseddrilling fluids are used in the present invention, such oil-baseddrilling fluids may comprise an emulsified aqueous phase that allows themodified water-soluble polymer to be incorporated into the oil-baseddrilling fluids.

The water-soluble relative permeability modifier generally should bepresent in the drilling fluids in an amount sufficient to provide thedesired degree of permeability modification. In an exemplary embodiment,the water-soluble relative permeability modifier is present in thedrilling fluids of the present invention in an amount in the range offrom about 0.02% to about 10% by weight of the drilling fluid. In anexemplary embodiment, the water-soluble relative permeability modifieris present in the drilling fluids of the present invention in an amountin the range of from about 0.05% to about 1.0% by weight of the drillingfluid.

Additional additives may be added to the drilling fluids of the presentinvention as deemed appropriate by one skilled in the art for improvingthe performance of the drilling fluids with respect to one or moreproperties. Examples of such additives include, but are not limited to,emulsifiers, viscosifiers, fluid loss additives, salts, shale swellinginhibitors, weighting agents, and numerous other additives suitable foruse in drilling operations.

While a number of exemplary embodiments described herein relate todrilling fluids, it is to be understood that the relative permeabilitymodifiers of the present invention may be placed into the subterraneanformation as part of other well bore fluids, used in the drilling phase,such as drill-in fluids and completion fluids.

Some embodiments of the present invention provide a method of reducingthe permeability of a subterranean formation to aqueous-based fluidsduring the drilling phase that comprises the steps of providing awater-soluble relative permeability modifier that comprises ahydrophobically modified polymer; and placing the water-soluble relativepermeability modifier into the subterranean formation during thedrilling phase.

Another embodiment of the present invention provides a method ofreducing the permeability of a subterranean formation to aqueous-basedfluids during the drilling phase that comprises the steps of providing awater-soluble relative permeability modifier that comprises ahydrophilically modified polymer; and placing the water-soluble relativepermeability modifier into the subterranean formation during thedrilling phase.

Another embodiment of the present invention provides a method ofreducing the permeability of a subterranean formation to aqueous-basedfluids during the drilling phase that comprises the steps of providing awater-soluble relative permeability modifier that comprises awater-soluble polymer without hydrophobic or hydrophilic modification;and placing the water-soluble relative permeability modifier into thesubterranean formation during the drilling phase.

Some embodiments of the present invention provide a method of drilling awell bore in a subterranean formation that comprises the steps ofproviding a drilling fluid that comprises a base fluid, and awater-soluble relative permeability modifier that comprises ahydrophobically modified polymer; and placing the drilling fluid in thewell bore in the subterranean formation.

Another embodiment of the present invention provides a method ofdrilling a well bore in a subterranean formation that comprises thesteps of providing a drilling fluid that comprises a base fluid, and awater-soluble relative permeability modifier that comprises ahydrophilically modified polymer; and placing the drilling fluid in thewell bore in the subterranean formation.

Another embodiment of the present invention provides a method ofdrilling a well bore in a subterranean formation that comprises thesteps of providing a drilling fluid that comprises a base fluid, and awater-soluble polymer without hydrophobic or hydrophilic modification;and placing the drilling fluid in the well bore in the subterraneanformation.

Another embodiment of the present invention provides a drilling fluidthat comprises a base fluid, and a water-soluble relative permeabilitymodifier that comprises a hydrophobically modified polymer.

Yet another embodiment of the present invention provides a drillingfluid that comprises a base fluid, and a water-soluble relativepermeability modifier that comprises a hydrophilically modified polymer.

To facilitate a better understanding of the present invention, thefollowing examples of the preferred embodiments are given. In no wayshould the following examples be read to limit, or define, the scope ofthe invention.

EXAMPLES

Permeability reduction tests were performed using two treatmentsolutions and a multipressure tap Hassler sleeve containing a Bereasandstone core. These permeability reduction tests were performed at175° F. Further, Test No. 1 was conducted using a brine containing 2% byweight potassium chloride, and Test No. 2 was conducted using a brinecontaining 7% potassium chloride. Two treatment solutions were preparedfor this series of tests.

The treatment solution used in Test No. 1 comprised 5,000 ppm of asample polymer and 500 ppm of “ARQUAD® DMCB 80” dissolved in 2%potassium chloride brine. “ARQUAD® DMCB 80” is a surfactant that iscommercially available from Akzo Nobel Inc., Chicago, Ill. The samplepolymer comprises a hydrophobically modified polymer that comprises apolymer backbone comprising polar heteroatoms formed from the reactionof a cationic starch and an organic acid derivative, such as octenylacid or dodecenyl succinic acid.

The treatment solution used in Test No. 2 comprised 5,000 ppm of thesample polymer dissolved in 7% potassium chloride brine.

The following procedure was used for this series of tests, the resultsof which are provided in Table 1. For each test, the above-describedbrines were flowed through the Berea core, followed by oil (kerosene),followed by brine. This third brine flow was maintained until thepressure stabilized, yielding an initial brine permeability. Next, atreatment solution was flowed into the core. Next, the brine flow wasreestablished until the pressure stabilized, yielding a finalpermeability from which the brine permeability was calculated using theformula [1-(final permeability/initial permeability)]×100. Themultipressure tap Hassler sleeve allowed the core permeability to bedivided into four segments. In the tests, the initial brine flow wasfrom segment 1 to segment 4. The treatment solution flow was fromsegment 4 to segment 1, and the final brine flow was from segment 1 tosegment 4. The results of the tests are provided below in Table 1.

TABLE 1 Sample Polymer Initial Water Water Concentration SurfactantPermeability Permeability Test (ppm) Brine Surfactant Concentration(milli Darcy) Reduction Test 5000 2% ARQUAD 500 ppm 90 85% No. 1 KCLDMCB-80 Test 5000 7% None None 120 69% No. 2 KCL

This example indicates, inter alia, that a water-soluble relativepermeability modifier of the present invention may reduce thepermeability of a subterranean formation to aqueous-based fluids.

Therefore, the present invention is well adapted to carry out theobjects and attain the ends and advantages mentioned as well as thosewhich are inherent therein. While numerous changes may be made by thoseskilled in the art, such changes are encompassed within the spirit ofthis invention as defined by the appended claims.

1.-68. (canceled)
 69. A drilling fluid for use in a well bore in a subterranean formation comprising: a base fluid and a hydrophobically modified polymer, the hydrophobically modified polymer consisting of alkyl chains having a carbon chain length between about 4 and about 22 carbons bound to a hydrophilic polymer, wherein the hydrophilic polymer: consists of a polymer backbone that contains polar heteroatoms, at least one of which is not a nitrogen atom, and at least a portion of the polar heteroatoms are functionalized with the alkyl chains; and, comprises at least one hydrophilic polymer selected from the group consisting of a cellulose, a chitosan, a polyetheramine, a polyhydroxyetheramine, a polylysine, and a polysulfone.
 70. The drilling fluid of claim 69 wherein the hydrophobically modified polymer has a molecular weight in the range of from about 100,000 to about 10,000,000.
 71. The drilling fluid of claim 69 wherein the polar heteroatoms comprise at least one polar heteroatom selected from the group consisting of oxygen, nitrogen, sulfur, and phosphorous.
 72. The drilling fluid of claim 69 wherein the hydrophobic compound is selected from the group consisting of an alkyl halide, a sulfonate, an organic acid derivative, and a combination thereof.
 73. The drilling fluid of claim 69 wherein the hydrophobic compound is an organic acid derivative selected from the group consisting of an octenyl succinic acid; a dodecenyl succinic acid; an anhydride; an ester; an amide of octenyl succinic acid; an amide of dodecenyl succinic acid; and combinations thereof.
 74. The drilling fluid of claim 69 wherein the water-soluble relative permeability modifier is present in the drilling fluid in an amount in the range of from about 0.02% to about 10% by weight of the drilling fluid.
 75. The drilling fluid of claim 69 wherein the water-soluble relative permeability modifier is present in the drilling fluid in an amount in the range of from about 0.05% to about 1% by weight of the drilling fluid.
 76. A drilling fluid for use in a well bore in a subterranean formation comprising: a base fluid and a hydrophobically modified polymer, the hydrophobic compound consisting of an alkyl halide having a carbon chain length between about 4 and about 22 carbons, and the hydrophilic polymer: consists of a polymer backbone that contains polar heteroatoms, at least one of which is not a nitrogen atom, and at least a portion of the polar heteroatoms are functionalized with the alkyl chains; and, comprises at least one hydrophilic polymer selected from the group consisting of a cellulose, a chitosan, a polyetheramine, a polyhydroxyetheramine, a polylysine, and a polysulfone.
 77. The drilling fluid of claim 76 wherein the hydrophobically modified polymer has a molecular weight in the range of from about 100,000 to about 10,000,000.
 78. The drilling fluid of claim 76 wherein the polar heteroatoms comprise at least one polar heteroatom selected from the group consisting of oxygen, nitrogen, sulfur, and phosphorous.
 79. The drilling fluid of claim 76 wherein the water-soluble relative permeability modifier is present in the drilling fluid in an amount in the range of from about 0.02% to about 10% by weight of the drilling fluid.
 80. The drilling fluid of claim 76 wherein the water-soluble relative permeability modifier is present in the drilling fluid in an amount in the range of from about 0.05% to about 1% by weight of the drilling fluid. 